Homolytic Cleavage of Molecular Oxygen by Manganese Porphyrins Supported on Ag(111)
نویسندگان
چکیده
منابع مشابه
Homolytic cleavage of molecular oxygen by manganese porphyrins supported on Ag(111).
Oxygen binding and cleavage are important for both molecular recognition and catalysis. Mn-based porphyrins in particular are used as catalysts for the epoxidation of alkenes, and in this study the homolytic cleavage of O2 by a surface-supported monolayer of Mn porphyrins on Ag(111) is demonstrated by scanning tunneling microscopy, X-ray absorption, and X-ray photoemission. As deposited, {5,10,...
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ژورنال
عنوان ژورنال: ACS Nano
سال: 2014
ISSN: 1936-0851,1936-086X
DOI: 10.1021/nn501240j